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ON THE SCIENCE OF WEIGHING AND MEASURING, AND THE STANDARDS OF

WEIGHT AND MEASURE*

IX.

IN the comparison of standard weights, the difficulty and risk of error in determining the weight of air displaced by them is to be avoided by weighing them not in air, but in a vacuum. Two methods are employed for this kind of weighing.

In the first and simplest method, when an ordinary balance of precision is used, each standard weight is placed in an exhausted receiver just large enough to hold

it, and is weighed separately against a counterpoise by been found in the results of this method of weighing in Borda's method. Sensible discordances have, however, exhausted receivers, which render its use inexpedient when scientific accuracy is required. These discordances are perhaps attributable to a small quantity of air being present in the receiver during the weighings, the amount of which cannot be accurately determined. Another probable cause is a change in the temperature and atmospheric pressure affecting the balance itself and the weights in the pans during the long time necessarily occupied in the whole process of this method of weighing. Indeed it may be generally stated as a rule that the risk of discordances in the results of weighings is in proportion

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to the time occupied in the operation. Such discordances are not found when the weighings are made by the second method, when a vacuum balance is used, that is to say, when the balance case itself is made an exhausted receiver.

A vacuum balance has been constructed at Paris by M. Deleuil, and is now used at the Conservatoire des Arts et Métiers, consisting of a balance of the best construction placed in a very strong cast-iron case that can be made perfectly air-tight. This case has four circular openings for giving admittance and light to the inside, which are closed with strong glass covers. It has a * Continued from p. 49.

stuffing box for the handle of the lever by which the balance is put in action and arrested. This balance has been found to give very accurate results of weighing in a vacuum. But the comparison of standard weights in this vacuum balance takes a considerable time from the necessity of opening the case and re-establishing a va cuum at least a second time in order to change the weights in the pans even when Borda's method is used; and occasionally this must be done again if a small additional balance weight is required to be placed in either pan, in order to obtain a sufficiently approximate equilibrium, so that the pointer may not exceed the limits of the index scale.

Some improvements on Deleuil's vacuum balance have been designed by Prof. W. H. Miller, and have been practically carried out in a vacuum balance constructed by Mr. Oertling for the Standards Department. The balance case consists of a strong brass frame cast in one piece, with a rectangular base, two sides, and an arched top. Two solid glass plates, each 1 in. thick, form the front and back of the case, being clamped to plane surfaces of the brass frame, and made air-tight by interposing thin india-rubber. They are thus removable when required, for instance, when any alteration is needed in the balance. There is a circular opening 49 in. in diameter, on each side of the brass frame, similar to those on Deleuil's balance, to which glass covers are fitted. There is no stuffing-box, but when the Standard weights to be compared are placed in the pans, and the balance case exhausted, contrivances are arranged for putting the balance in action and arresting it, for adding any balance weights to either pan and removing them, and for interchanging the pans and weights by transferring them to the other end of the beam, without any disturbance of the vacuum, or necessity of opening the case.

These arrangements enable the weighings to be made by Gauss's method of alternation. The balance case is firmly placed upon a strong mahogany stand. Two iron tubes are fixed underneath and opening into the balance case. They rest in iron cups containing a sufficient quantity of mercury. Within each tube is a steel rod rising to the required height inside the balance case, and having at the top an arm of convenient form. By means of a simple lever handle outside the tube, either rod can be lifted about an inch, and it can also be turned round. By this rotary motion, when the left-hand rod is in its normal position, it acts upon two bevelled wheels, and thus lowers the supporting frame of the beam and puts the balance in action; and by reversing the motion, the action is stopped. By raising either rod to nearly its full height, it can be made to take up one of several small balance weights riding on a little rail fixed to the pillar of the balance, and transfer it to a similar rail at the top of the pan, or to transfer it back again. Again by raising either steel rod to an intermediate height, and turning its arm under the arched rods of one of the pans, and then raising it a little, the pan and weight can be lifted off the hook of the beam and transposed to a small carriage standing upon a railroad near and parallel to the front of the balance-case. In a similar way the other pan and weight can be transferred to a second carriage at the back of the case. By means of a cord and pulleys, one of which is upon the right-hand steel rod and can thus be turned round with the hand, the two carriages can be moved to the other ends of the case, and then each pan with its weight can be attached to the hook at the other end of the beam. The desired results are all thus attained, and the whole action of the balance is open to view.

The construction of this new vacuum balance may be seen from Fig. 19.

The balance itself is similar in construction to the other Standard balances made by Mr. Oertling. It is constructed to weigh a kilogram in each pan. There are two Standard thermometers inside the case, one fixed to each pillar, and adjustible as to height, so that its bulb may be on the same level as the centre of gravity of the weight. A mercurial gauge is fixed between the pillars, and there is the same arrangement of three tubes and stopcocks communicating with air-pumps and with a mano-barometer, as in Deleuil's vacuum balance. Two glass vessels containing chloride of calcium, are also introduced for absorbing any moisture in the balance case.

There are two ways of comparing and verifying standard measures of capacity. The first and most accurate, as well as scientific method, is by weighing their contents of distilled water; the second method, which is simpler and

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more ordinarily used, consists in comparing the measure of water contained in them, with the contents of a verified standard measure.

In weighing the contents of distilled water contained in a standard measure, when quite full to the brim, and with the surface of the water made accurately level by a disc of plate glass slid over it, Borda's method of weighing is employed. The measure with its disc is placed empty in one of the pans of the balance, and is accurately counterpoised. A verified standard weight equal to the legal weight of water contained in the measure is then added to the pan containing the measure and disc, and is accurately counterpoised, and a sufficient number of weighings is taken until the mean resting-point of the balance is determined and noted. The standard weight is then removed. The measure is exactly filled with distilled water, and its temperature, together with the reading of the barometer noted. Any difference in the actual temperature and barometric pressure from the normal temperature and pressure is to be compensated by equivalent weights placed either in the measure pan or weight pan as required. If an equipoise is not now obtained, additional weights are placed in the pan until an equilibrium is produced, and any difference from the normal correcting weight for temperature and barometric pressure

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either plus or minus, shows the error of the measure in relation to its legal weight of water at the standard temperature and barometric pressure.

For ascertaining the exact amount of the proper corrections for temperature and barometric pressure, authoritative tables are computed both for Imperial and for Metric Measures. Such tables will be found in the Papers appended to the Fifth Report of the Standards Commission, published in 1871 (pp. 81, 193, and 196), and to the Sixth Annual Report of the Warden of the Standards, published in 1872 (pp. 49 and 51).

With regard to comparing instruments for standard measures of length, their construction has necessarily varied according to the form of the standard measure. As has been already stated, the earlier scientific standards of length were defined by two points, and all comparisons were made by means of a beam compass.

The introduction by Mr. Troughton of the use of the micrometer microscope was a great step in advance towards the attainment of scientific accuracy in the comparison of our standard measures of length. It enabled optical observations to be made without injurious contact to the defining points or lines, and thus without interference with the permanence of the

measures. Several descriptions of comparing apparatus with micrometer microscopes have been constructed at various times, but all are made upon the same principle. The microscope is fixed in a vertical position, and is provided with a spirit level and with screws for accurate levelling and focal adjustment. The defining marks of the two standard measures to be compared are brought successively under it, their height being adjusted to the focal distance of the microscope. Any difference of length between the defining marks of the two measures is read off from the graduated head of the micrometer. This part of the apparatus consists of an endless screw with the very finest threads, having a large head divided into 100 parts. The screw is placed in a horizontal position, and when turned carries with it a nut moving in horizontal guides, together with an open frame, which has cobweb lines stretched across it. Two of these lines (bb Fig. 20) cross each other at equal angles to the axis of the screw, and so that a line bisecting them is normal to its axis. Two other lines (c c) are placed nearly close, and parallel to each other and normal to the axis of the screw; and there are two longitudinal lines (dd) parallel to the axis of the screw, by means of which this axis is made parallel to the axis of the measure under observation. When turning the screw, the number of revolutions is read off by the aid of a pointer from a rack (a) placed at the edge of the open frame and parallel to the screw, whilst the number of divisions in one revolution is read off on the graduated head of the screw, from a fixed line marked on the upper surface of the microscope. Looking through the eye-piece of the microscope at the magnified first ten hundredths of the inch 36-37 marked on the subdivided standard yard of the Standards' Department (here inverted), the field of the microscope is seen as represented in Fig. 20.

In this figure the cross lines are used for observation, and are seen adjusted to the o'03 in. line. The pointer at the rack shows the screw to be turned between one and two revolutions from the middle of the field.

All micrometer microscopes used for the comparison of standard measures of length are constructed upon the principle thus described. But there are various kinds of arrangements for supporting the standard measures in a proper position, and for more conveniently bringing their defining marks under the microscopes. Under one of the arrangements, a single micrometer microscope is used, and fixed over the supporting apparatus, which, for the purpose of comparison, has both a transversal and a longitudinal displacement.

The two standard measures (denoted as A and B) being placed with their axes exactly parallel, and their defining marks as nearly as possible in the same line normal to the axes, the left-hand defining mark of A is brought under the microscope, and the position of the micrometer read off on the index scale and noted. By the transversal displacement, the left-hand defining mark of B is next brought under the microscope, and the reading of the index scale noted. The two measuring bars are then moved their whole length by longitudinal displacement, and the right-hand defining marks of A and B successively read off and noted, thus affording the means of ascertaining the difference of length of the two standard measures. The temperature of the bars at the beginning and end of the observations must be determined by thermometers, and the mean temperature noted, and allowance must be made by computation for any difference of length arising from unequal expansion or contraction of the two bars, when this temperature differs from the standard temperature. For this purpose it is absolutely necessary that the coefficient of expansion of each standard bar must be previously determined.

This method of comparing with a single microscope is used in France, but not in England, where the risk of error arising from the longitudinal movement of the bars

is avoided by using two microscopes, and only a transversal displacement of the bars during the observations, although there are also means of longitudinal displacement for the purposes of adjustment. The objection raised against the use of two microscopes, that the distance between them may vary during the period of observation by the expansion or contraction from alteration of temperature of the material which unites them, is obviated by fixing them firmly and independently upon a solid stone support.

Placing measuring bars directly upon a plane support is objectionable. It has been proved that there is a risk of discordances in comparisons being caused by almost undiscoverable inequalities in planed surfaces, as well as by a difference of temperature in the plane surface and the under surface of the measuring bar, when thus placed. To guard against this risk, the bars are supported upon rollers, and the measuring bars ought to be stift enough to bear to be supported upon a few points at which rollers can be conveniently applied. For a short bar two rollers are sufficient; for a longer bar more supports are required. The standard yard bars are supported upon eight rollers, and it is always requisite that each support should exert the same vertical pressure upwards, in order that the interval between two points upon the surface of the bar may not be altered by the flexure. This object is attained by a proper arrangement of levers; and it is easily seen that an arrangement of levers by which equal pressure upwards may be exerted at four or eight points is very simple. Each bar rests upon two brass lever-frames. It has been shown by the Astronomer Royal, in his paper printed in the Royal Astronomical Society's Memoirs, vol. xv., that the value of the intervals (supposed equal) which ought to exist between different supports of a bar, each support exerting the same vertical pressure upwards, is as follows: n being the number of supports, the resulting intervals of supports is :

length of bar

√ (n2 − 1).

In order to ascertain with scientific precision how far the results of comparisons of standards obtained by the use of weighing and measuring instruments are to be depended upon for their accuracy, a calculation is to be made of the probable error of every such result, whether it be the result of a single comparison, or the mean result of any number of comparisons. And when other elements are to be taken into account, it is necessary that the probable error of each computation should be determined and allowed for before the final results of comparison can be determined and allowed for.

The mode generally adopted for calculating the probable error is based upon the method of least squares, and is fully stated by the Astronomer Royal, in his "Theory of Errors of Observation," pp. 44-7.

You

H. W. CHISHOLM

EARTH-SCULPTURE* II.

YOU are aware that the revival of the half-forgotten doctrines of the early Scottish School of Geology has not been without vehement protest on the part of the older geologists, who have been inclined to treat them rather as novelties and departures from the older and purer faith. No one resisted them more determinedly than my much-missed friend and benefactor, the late Sir Roderick Murchison. He looked with regret, and even, perhaps, sometimes with a little alarm, upon their advance, and to the last he battled against them. He was, indeed, in this country the leader of his party, which has been called the Convulsionist School," and his death

Opening Address to the Edinburgh Geological Society, by Prof. Geikie F.R.S. (continued from p. 52).

has, doubtless, been a severe blow to that school, as it has been a loss to all who admired a straightforward, courteous, and undaunted antagonist.

Other members of the party have, however, in more or less direct ways, lifted up their voices of protest. I select this evening one of these antagonists, partly because he has spoken more and more energetically than any other, and partly because a good deal of his speaking has been directed against myself. And here I am sorry that I must begin by a reference to a matter of personal history. In the summer of 1865 I published a little volume, now out of print, on "The Scenery of Scotland, viewed in connection with its Physical Geology." The object of that work was to show how completely the Huttonian doctrine of earth-sculpture was borne out by the mountains and valleys of the northern part of this island. distinctly disclaimed any novelty or originality on my own part in the broad doctrine which I tried to enforce. My veneration for Hutton and Playfair had been from boyhood profound; again and again in the pages of my book I quoted them, and spoke of them as the founders of the school to which I professed myself a loyal adherent, and in which I could boast such friends and colleagues as Jukes and Ramsay.

I

I was well aware, and stated in the preface, that the views to which I had been led "ran counter to what are still the prevailing impressions on this subject," and that I was prepared to find them disputed, or thrown aside. Convinced, however, of their essential truth, I looked forward to a time when what might then be regarded as mere dreaming would be established as a recognised part of the groundwork of geology. The views put forward in the volume met, indeed, with an amount of general acceptance which I could hardly have anticipated. But at length the expected opposition made its appearance.

On February 3, 1868, his Grace the Duke of Argyll read to the Geological Society of London a paper, entitled "On the Physical Geography of Argyleshire, in connection with its geological structure." Although that title was chosen, the paper proved really to be from beginning to end a criticism of my little book, which, indeed, the author candidly acknowledged to have served him as "the best text he could find."

But a broad challenge addressed to the general body of geologists by the President in the official Address which he annually gives to the Society and the world, is not the same thing as a criticism from one member of the Society upon the work of another member. In the interests of science, therefore, it seems to me that some protest is now called for against doctrines promulgated at this late date in the century from so high and honourable position as the Chair of the Geological Society of London; and as I have been especially singled out for attack, it appears to me to be only an act of duty to vindicate, not my own position merely, but the reputation of that "younger school" which is accused of seeking to pervert the geological mind from the ancient and true creed. If these doctrines maintained by the President were to become generally diffused, which, happily, is now impossible, they would suffice to paralyse research in one important branch of the science; for, as far as relates to the history of the configuration of the land, they would assuredly bring down upon us again the pre-Huttonian darkness. No one whom the Geological Society of London has chosen as its President can fail to command the respectful attention of geologists all over the world. And while I gladly acknowledge this right, I would also express the gratification which is widespread among the brethren of the hammer in this country that the Duke of Argyll, in the midst of so many and so onerous, as well as honourable duties, should find time to take a lively and active interest in the progress of geology. I admire, too, the vigour with which he wields his pen, and the boldness with which he gives his judgment among disputed questions. He has once more thrown down his geological gauntlet, and if I venture to take it up, and accept his battle, it is in the full consciousness of the presence of an adversary who, while dealing hard blows himself, will take in good part such buffets as the fortunes of war may bring to him.

I have already alluded to the natural impression that when we look at a region of rough mountains formed out of hardened and contorted rocks, we behold in the external outlines the direct results of the subterranean force by which the rocks were altered and crumpled. This obvious inference is far older than the days of geological inquiry. But surely its mere obviousness is no argument for its truth, any more than the rising and setting of the sun prove the earth to be the centre of the universe. the volume already referred to I spoke of it as "dealing with that dreamland of conjecture and speculation lying far beyond the pathways of science, where one has no need of facts for either the foundation or superstructure of his theory. It thus requires no scientific knowledge or training; it can be appreciated by all, and may be applied

In

To that paper I made no reply. It seemed to me that the noble author had failed to perceive the bearing of the whole argument from geological waste, as proved by geological structure. His objections being already, in my opinion, anticipated in the book which had called them forth, I did not see how I could make my case plainer by any amount of additional argument. But further, his Grace had begun his communication with a sentence in which he stated that the views set forth by me "seemed to be gaining ground with the younger school of geolo-to the history of a mountain chain by one to whom the gists," fatal admission, as it occurred to me, for I felt that what was called the younger school must eventually take the place of that which styled itself the older, and that if it remained true to its belief, the views which were now called in question would carry the day without any battling of mine. Every month shows more fully the justice of this anticipation.

I was content to let the matter rest; nor would I recur to it now, but for the following reasons. Since that time the Duke of Argyll has become President of the Geological Society of London. In his recent address, and in a separate communication to the Society, he has returned to the subject of the origin of the present features of the land, referring to his former paper as an argument which had not been met by any answer in detail,” and adhering, therefore, to the views there expressed. As to the nonappearance of any "answer in detail" from myself, I can give no other explanation than that I considered my little book sufficiently detailed for its purpose, and believed that it already anticipated and answered the argument of my opponent. That is still my belief.

very name of geology is unknown." But to recognise that this common and instinctive notion is yet a misleading one, requires an acquaintance with geological structure which comparatively few have an opportunity of obtaining, and which appears to be not always readily acquired at second-hand. I have watched the current geological literature on this question during the last decennium, and the result has been to convince me that the notion, or rather the prejudice which I am combating, is in some minds so deeply rooted that it cannot be got rid of by the reading of any number of books or treatises, and, of course, still less by the writing of them. Simple as may be the statement of the leading principles and facts relative to that waste of the earth's surface to which the term Denudation is applied, there is yet, I firmly believe, no part of geology more difficult adequately to realise. So striking are the difference and contrast between the magnitude of the results adduced and the apparent insignificance and impotence of the forces which are alleged to have produced them, that the mind not unnaturally hesitates to associate the one with the other in the rela

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