Atomic and Molecular Spectroscopy: Basic Aspects and Practical ApplicationsSpringer Science & Business Media, 04/12/2003 - 580 páginas Atomic and Molecular Spectroscopy is a wide-ranging review of modern spectroscopic techniques such as X-ray, photoelectron, optical and laser spectroscopy, and radiofrequency and microwave techniques. On the fundamental side it focuses on physical principles and the impact of spectroscopy on our understanding of the building blocks of matter, while in the area of applications particular attention is given to those in chemical analysis, photochemistry, surface characterisation, environmental and medical diagnostics, remote sensing and astrophyscis. The Fourth Edition also provides the reader with an update on laser cooling and trapping, Bose-Einstein condensation, ultra-fast spectroscopy, high-power laser/matter interaction, satellite-based astronomy and spectroscopic aspects of laser medicine. Important references are also brought up to date. |
Índice
1 Introduction | xvii |
2 Atomic Structure | 1 |
22 Alkali Atoms | 3 |
23 Magnetic Effects | 4 |
232 SpinOrbit Interaction | 5 |
24 General ManyElectron Systems | 6 |
25 The Influence of External Fields | 13 |
251 Magnetic Fields | 14 |
72 Microwave Radiometry | 214 |
73 Radio Astronomy | 218 |
Lasers | 223 |
82 Coherence | 226 |
83 Resonators and Mode Structure | 227 |
84 FixedFrequency Lasers | 232 |
842 FourLevel Lasers | 234 |
843 Pulsed Gas Lasers | 237 |
252 Electric Fields | 17 |
26 Hyperfine Structure | 19 |
262 Electric Hyperfine Structure | 21 |
27 The Influence of External Fields hfs | 22 |
28 Isotopic Shifts | 25 |
3 Molecular Structure | 27 |
31 Electronic Levels | 28 |
32 Rotational Energy | 31 |
33 Vibrational Energy | 32 |
34 Polyatomic Molecules | 33 |
35 Clusters | 35 |
36 Other Molecular Structures | 36 |
4 Radiation and Scattering Processes | 37 |
42 Spectra Generated by Dipole Transitions | 47 |
421 Atoms | 48 |
422 Molecules | 51 |
43 Rayleigh and Raman Scattering | 57 |
44 Raman Spectra | 59 |
442 Rotational Raman Spectra | 60 |
45 Mie Scattering | 61 |
46 Atmospheric Scattering Phenomena | 62 |
47 Comparison Between Different Radiation and Scattering Processes | 65 |
48 CollisionInduced Processes | 66 |
Spectroscopy of Inner Electrons | 67 |
511 XRay Emission Spectroscopy | 69 |
512 XRay Absorption Spectroscopy | 75 |
513 XRay Imaging Applications | 78 |
52 Photoelectron Spectroscopy | 81 |
521 XPS Techniques and Results | 83 |
522 Chemical Shifts | 86 |
53 Auger Electron Spectroscopy | 91 |
Optical Spectroscopy | 93 |
611 Line Light Sources | 94 |
612 Continuum Light Sources | 102 |
613 Synchrotron Radiation | 104 |
614 Natural Radiation Sources | 109 |
62 Spectral Resolution Instruments | 110 |
622 Grating Spectrometers | 113 |
623 The Fabry Perot Interferometer | 117 |
624 The Fourier Transform Spectrometer | 122 |
63 Detectors | 124 |
64 Optical Components and Materials | 130 |
642 Absorption Filters | 134 |
643 Polarizers | 137 |
644 Optical Materials | 139 |
645 Influence of the Transmission Medium | 140 |
65 Optical Methods of Chemical Analysis | 144 |
651 The BeerLambert Law | 145 |
652 Atomic AbsorptionEmission Spectrophotometry | 147 |
653 Burners Flames Sample Preparation and Measurements | 151 |
654 Modified Methods of Atomization | 152 |
655 MultiElement Analysis | 153 |
656 Molecular Spectrophotometry | 154 |
657 Raman Spectroscopy | 156 |
66 Optical Remote Sensing | 158 |
661 Atmospheric Monitoring with Passive Techniques | 160 |
662 Land and Water Measurements with Passive Techniques | 167 |
67 Astrophysical Spectroscopy | 172 |
RadioFrequency Spectroscopy | 183 |
712 AtomicBeam Magnetic Resonance | 185 |
713 Optical Pumping | 193 |
714 Optical Double Resonance | 196 |
715 LevelCrossing Spectroscopy | 199 |
716 Resonance Methods for Liquids and Solids | 205 |
844 The HeNe Laser | 239 |
845 Gaseous Ion Lasers | 240 |
85 Tunable Lasers | 242 |
852 ColourCentre Lasers | 251 |
853 Tunable SolidState Lasers | 252 |
854 Tunable CO2 Lasers | 253 |
855 Semiconductor Lasers | 255 |
86 Nonlinear Optical Phenomena | 258 |
87 Ultrashort and UltrahighPower Laser Pulse Generation | 272 |
872 Generation of Ultrahigh Power Pulses | 278 |
Laser Spectroscopy | 283 |
913 Excitation Methods | 285 |
915 Laser Wavelength Setting | 288 |
92 DopplerLimited Techniques | 290 |
923 Absorption Measurements on Excited States | 293 |
925 TwoPhoton Absorption Measurements | 295 |
926 OptoGalvanic Spectroscopy | 297 |
927 SingleAtom and SingleMolecule Detection | 300 |
and LevelCrossing Experiments with Laser Excitation | 302 |
94 TimeResolved Atomic and Molecular Spectroscopy | 307 |
941 Generation of Short Optical Pulses | 308 |
943 Background to Lifetime Measurements | 314 |
944 Survey of Methods of Measurement for Radiative Properties | 315 |
945 QuantumBeat Spectroscopy | 321 |
95 Ultrafast Spectroscopy | 327 |
951 Ultrafast Measurement Techniques | 328 |
952 Molecular Reaction Dynamics Femtochemistry | 332 |
953 Coherent Control | 334 |
96 HighPower Laser Experiments | 335 |
961 Above Threshold lonization ATI | 336 |
962 High Harmonic Generation | 338 |
963 XRay Laser Pumping | 343 |
964 Broadband XRay Generation | 344 |
965 Relativistic Effects and Laser Accelerators | 347 |
971 Spectroscopy on Collimated Atomic and Ionic Beams | 348 |
972 Saturation Spectroscopy and Related Techniques | 355 |
973 DopplerFree TwoPhoton Absorption | 364 |
98 Cooling and Trapping of Ions and Atoms | 370 |
982 Ion Traps | 372 |
983 Basic Laser Cooling in Traps | 373 |
984 Trapped Ion Spectroscopy | 375 |
986 SubRecoil Cooling | 378 |
987 Atom Optics | 380 |
989 Ultracold Fermionic Gases | 383 |
LaserSpectroscopic Applications | 385 |
1013 Raman Spectroscopy | 394 |
1015 Velocity Measurements | 399 |
102 Laser Remote Sensing of the Atmosphere | 402 |
1021 Optical Heterodyne Detection | 403 |
1022 LongPath Absorption Techniques | 404 |
1023 Lidar Techniques | 410 |
and Raman Spectroscopy in Liquids and Solids | 421 |
1031 Hydrospheric Remote Sensing | 422 |
1032 Vegetation Monitoring | 425 |
1033 Monitoring of Surface Layers | 426 |
104 LaserInduced Chemical Processes | 431 |
1042 Laser Isotope Separation | 432 |
105 Spectroscopic Aspects of Lasers in Medicine | 437 |
1052 Photodynamic Tumour Therapy | 439 |
1054 Scattering Spectroscopy and Tissue Transillumination | 450 |
Questions and Exercises | 457 |
References | 469 |
571 | |
Outras edições - Ver tudo
Atomic and Molecular Spectroscopy: Basic Aspects and Practical Applications Sune Svanberg Pré-visualização limitada - 2012 |