Atomic and Molecular Spectroscopy: Basic Aspects and Practical Applications

Capa
Springer Science & Business Media, 04/12/2003 - 580 páginas

Atomic and Molecular Spectroscopy is a wide-ranging review of modern spectroscopic techniques such as X-ray, photoelectron, optical and laser spectroscopy, and radiofrequency and microwave techniques. On the fundamental side it focuses on physical principles and the impact of spectroscopy on our understanding of the building blocks of matter, while in the area of applications particular attention is given to those in chemical analysis, photochemistry, surface characterisation, environmental and medical diagnostics, remote sensing and astrophyscis. The Fourth Edition also provides the reader with an update on laser cooling and trapping, Bose-Einstein condensation, ultra-fast spectroscopy, high-power laser/matter interaction, satellite-based astronomy and spectroscopic aspects of laser medicine. Important references are also brought up to date.

 

Índice

1 Introduction
xvii
2 Atomic Structure
1
22 Alkali Atoms
3
23 Magnetic Effects
4
232 SpinOrbit Interaction
5
24 General ManyElectron Systems
6
25 The Influence of External Fields
13
251 Magnetic Fields
14
72 Microwave Radiometry
214
73 Radio Astronomy
218
Lasers
223
82 Coherence
226
83 Resonators and Mode Structure
227
84 FixedFrequency Lasers
232
842 FourLevel Lasers
234
843 Pulsed Gas Lasers
237

252 Electric Fields
17
26 Hyperfine Structure
19
262 Electric Hyperfine Structure
21
27 The Influence of External Fields hfs
22
28 Isotopic Shifts
25
3 Molecular Structure
27
31 Electronic Levels
28
32 Rotational Energy
31
33 Vibrational Energy
32
34 Polyatomic Molecules
33
35 Clusters
35
36 Other Molecular Structures
36
4 Radiation and Scattering Processes
37
42 Spectra Generated by Dipole Transitions
47
421 Atoms
48
422 Molecules
51
43 Rayleigh and Raman Scattering
57
44 Raman Spectra
59
442 Rotational Raman Spectra
60
45 Mie Scattering
61
46 Atmospheric Scattering Phenomena
62
47 Comparison Between Different Radiation and Scattering Processes
65
48 CollisionInduced Processes
66
Spectroscopy of Inner Electrons
67
511 XRay Emission Spectroscopy
69
512 XRay Absorption Spectroscopy
75
513 XRay Imaging Applications
78
52 Photoelectron Spectroscopy
81
521 XPS Techniques and Results
83
522 Chemical Shifts
86
53 Auger Electron Spectroscopy
91
Optical Spectroscopy
93
611 Line Light Sources
94
612 Continuum Light Sources
102
613 Synchrotron Radiation
104
614 Natural Radiation Sources
109
62 Spectral Resolution Instruments
110
622 Grating Spectrometers
113
623 The Fabry Perot Interferometer
117
624 The Fourier Transform Spectrometer
122
63 Detectors
124
64 Optical Components and Materials
130
642 Absorption Filters
134
643 Polarizers
137
644 Optical Materials
139
645 Influence of the Transmission Medium
140
65 Optical Methods of Chemical Analysis
144
651 The BeerLambert Law
145
652 Atomic AbsorptionEmission Spectrophotometry
147
653 Burners Flames Sample Preparation and Measurements
151
654 Modified Methods of Atomization
152
655 MultiElement Analysis
153
656 Molecular Spectrophotometry
154
657 Raman Spectroscopy
156
66 Optical Remote Sensing
158
661 Atmospheric Monitoring with Passive Techniques
160
662 Land and Water Measurements with Passive Techniques
167
67 Astrophysical Spectroscopy
172
RadioFrequency Spectroscopy
183
712 AtomicBeam Magnetic Resonance
185
713 Optical Pumping
193
714 Optical Double Resonance
196
715 LevelCrossing Spectroscopy
199
716 Resonance Methods for Liquids and Solids
205
844 The HeNe Laser
239
845 Gaseous Ion Lasers
240
85 Tunable Lasers
242
852 ColourCentre Lasers
251
853 Tunable SolidState Lasers
252
854 Tunable CO2 Lasers
253
855 Semiconductor Lasers
255
86 Nonlinear Optical Phenomena
258
87 Ultrashort and UltrahighPower Laser Pulse Generation
272
872 Generation of Ultrahigh Power Pulses
278
Laser Spectroscopy
283
913 Excitation Methods
285
915 Laser Wavelength Setting
288
92 DopplerLimited Techniques
290
923 Absorption Measurements on Excited States
293
925 TwoPhoton Absorption Measurements
295
926 OptoGalvanic Spectroscopy
297
927 SingleAtom and SingleMolecule Detection
300
and LevelCrossing Experiments with Laser Excitation
302
94 TimeResolved Atomic and Molecular Spectroscopy
307
941 Generation of Short Optical Pulses
308
943 Background to Lifetime Measurements
314
944 Survey of Methods of Measurement for Radiative Properties
315
945 QuantumBeat Spectroscopy
321
95 Ultrafast Spectroscopy
327
951 Ultrafast Measurement Techniques
328
952 Molecular Reaction Dynamics Femtochemistry
332
953 Coherent Control
334
96 HighPower Laser Experiments
335
961 Above Threshold lonization ATI
336
962 High Harmonic Generation
338
963 XRay Laser Pumping
343
964 Broadband XRay Generation
344
965 Relativistic Effects and Laser Accelerators
347
971 Spectroscopy on Collimated Atomic and Ionic Beams
348
972 Saturation Spectroscopy and Related Techniques
355
973 DopplerFree TwoPhoton Absorption
364
98 Cooling and Trapping of Ions and Atoms
370
982 Ion Traps
372
983 Basic Laser Cooling in Traps
373
984 Trapped Ion Spectroscopy
375
986 SubRecoil Cooling
378
987 Atom Optics
380
989 Ultracold Fermionic Gases
383
LaserSpectroscopic Applications
385
1013 Raman Spectroscopy
394
1015 Velocity Measurements
399
102 Laser Remote Sensing of the Atmosphere
402
1021 Optical Heterodyne Detection
403
1022 LongPath Absorption Techniques
404
1023 Lidar Techniques
410
and Raman Spectroscopy in Liquids and Solids
421
1031 Hydrospheric Remote Sensing
422
1032 Vegetation Monitoring
425
1033 Monitoring of Surface Layers
426
104 LaserInduced Chemical Processes
431
1042 Laser Isotope Separation
432
105 Spectroscopic Aspects of Lasers in Medicine
437
1052 Photodynamic Tumour Therapy
439
1054 Scattering Spectroscopy and Tissue Transillumination
450
Questions and Exercises
457
References
469
Index
571
Direitos de autor

Outras edições - Ver tudo

Palavras e frases frequentes

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Referências a este livro

Acerca do autor (2003)

Sune Svanberg is a professor of physics and head of the Atomic Physics Division of the Lund Institute of Technology. He is also the director of the multi-disciplinary Lund Laser Centre at the Lund University. He has extensive research experience in radiofrequency, optical and laser spectroscopy, and in the use of lasers in combustion diagnostics, environmental monitoring, and medical diagnostics and treatment, and is thus in good position to cover the vast scope of the book. Sune Svanberg has coauthored almost 500 papers and trained a large number or undergraduates and graduates in basic and applied atomic and molecular spectroscopy. He served extensively in international organisations and scientific advisory committees. He is a member of five academies and holds three honorary doctor degrees.

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